dc.contributor.author | Connon, Stephen | en |
dc.date.accessioned | 2022-12-14T11:17:32Z | |
dc.date.available | 2022-12-14T11:17:32Z | |
dc.date.issued | 2022 | en |
dc.date.submitted | 2022 | en |
dc.identifier.citation | Smith S.N., Trujillo C., Connon S.J., Catalytic, asymmetric azidations at carbonyls: achiral and meso-anhydride desymmetrisation affords enantioenriched ?-lactams, Organic and Biomolecular Chemistry, 20, 32, 2022, 6384 - 6393, 6384-6393 | en |
dc.identifier.issn | 14770520 | en |
dc.identifier.other | Y | en |
dc.description | PUBLISHED | en |
dc.description | 10.1039/d2ob01040b | en |
dc.description.abstract | An unprecedented organocatalytic process involving the asymmetric addition of azide to meso-anhydrides has been developed, promoted by novel sulfamide-substituted Cinchona alkaloid-based catalysts. Readily available glutaric anhydrides can be smoothly converted to enantioenriched hemi-acyl azides and from there to either γ-amino acids or γ-lactams. | en |
dc.format.extent | 6384-6393 | en |
dc.format.extent | 6384 | en |
dc.format.extent | 6393 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Organic and Biomolecular Chemistry | en |
dc.relation.ispartofseries | 20 | en |
dc.relation.ispartofseries | 32 | en |
dc.rights | Y | en |
dc.subject | azide | en |
dc.subject | γ-amino acids | en |
dc.subject | γ-lactams | en |
dc.subject | meso-anhydrides | en |
dc.title | Catalytic, asymmetric azidations at carbonyls: achiral and meso-anhydride desymmetrisation affords enantioenriched ?-lactams | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/connons | en |
dc.identifier.rssinternalid | 249087 | en |
dc.identifier.doi | http://dx.doi.org/10.1039/d2ob01040b | en |
dc.rights.ecaccessrights | openAccess | |
dc.identifier.orcid_id | 0000-0003-2984-9246 | en |
dc.identifier.uri | http://hdl.handle.net/2262/101875 | |