| dc.contributor.author | Senge, Mathias | |
| dc.date.accessioned | 2025-01-25T11:32:45Z | |
| dc.date.available | 2025-01-25T11:32:45Z | |
| dc.date.issued | 2023 | |
| dc.date.submitted | 2023 | en |
| dc.identifier.citation | Grover, N. and Cheveau, M. and Twamley, B. and Kingsbury, C.J. and Mattern, C.M. and Senge, M.O., Bicyclo[1.1.1]pentane Embedded in Porphyrinoids**, Angewandte Chemie - International Edition, 62, 26, 2023 | en |
| dc.identifier.other | Y | |
| dc.description.abstract | We report a two-step approach to obtain
synthetically versatile bicyclo[1.1.1]pentane (BCP) derivatives using Grignard reagents. This method allows
the incorporation of BCP units in tetrapyrrolic macrocycles and the synthesis of a new class of calix[4]pyrrole
analogues by replacing two bridging methylene groups
with two BCP units. In addition, a doubly N-confused
system was also formed in the presence of electron-withdrawing substituents at the BCP bridgeheads. The
pyrrole rings in BCP containing macrocycles exist in 1,3-alternate or αβαβ conformations, as observed from
single-crystal X-ray diffraction analyses and 2D NMRspectroscopy. | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Angewandte Chemie - International Edition; | |
| dc.relation.ispartofseries | 62; | |
| dc.relation.ispartofseries | 26; | |
| dc.rights | Y | en |
| dc.title | Bicyclo[1.1.1]pentane Embedded in Porphyrinoids** | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/sengem | |
| dc.identifier.rssinternalid | 259135 | |
| dc.identifier.doi | http://dx.doi.org/10.1002/anie.202302771 | |
| dc.rights.ecaccessrights | openAccess | |
| dc.identifier.orcid_id | 0000-0002-7467-1654 | |
| dc.identifier.uri | https://hdl.handle.net/2262/110743 | |
