Browsing Chemistry (Scholarly Publications) by Author "PLUNKETT, SHANE"
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From thioether substituted porphyrins to sulfur linked porphyrin dimers: An unusual SNAr via thiolate displacement?
SENGE, MATHIAS; MCCABE, THOMAS; RYAN, AOIFE; PLUNKETT, SHANE (2014)Treatment of meso 2-ethylhexyl-3-mercaptopropionate substituted porphyrins with base at room temperature generated a porphyrin thiolate anion which in situ reacted in a nucleophilic aromatic substitution (SNAr) reaction ... -
Synthesis and Reactivity of Allenylporphyrins
SENGE, MATHIAS; PLUNKETT, SHANE (2013)Several different methods have been utilized for the effective synthesis of a new class of porphyrins that contains the synthetically intriguing propadienyl (or allenyl) functional group. Of these approaches, successive ...