| dc.contributor.author | VIJ, JAGDISH KUMAR | |
| dc.date.accessioned | 2010-08-18T15:36:28Z | |
| dc.date.available | 2010-08-18T15:36:28Z | |
| dc.date.issued | 2001 | |
| dc.date.submitted | 2001 | en |
| dc.identifier.citation | Johari, G.P., Kalinovskaya, O.E., Vij, J.K., Effects of induced steric hindrance on the dielectric behavior and H bonding in the supercooled liquid and vitreous alcohol , Journal of Chemical Physics, 114, 10, 2001, 4634 - 4642 | en |
| dc.identifier.other | Y | |
| dc.description | PUBLISHED | en |
| dc.description.abstract | The reasons of Debye-type dielectric relaxation in monohydroxy alcohols were investigated by studying the effects of steric hindrance on dielectric behavior and hydrogen bonding in alcohols. Broadband dielectric spectroscopy of supercooled liquid and glassy states of alcohol was performed to study the effect of optical isomers on intermolecular hydrogen bonding. The results showed that the relaxation rates fit the power law equations with critical exponent of 13.4 compared to 2-4 required in mode-coupling theory. | en |
| dc.description.sponsorship | G.P.J. is grateful for the hospitality of Trinity College,
Dublin, Ireland, during his stay for the period of this study.
We are grateful to Professor W. Dannhauser ~now retired!
for donating to G.P.J. all samples of alcohols he and his
co-workers had studied in the 1960s and 1970s. This research
was supported by a NSERC general research grant to
G.P.J. and by Enterprise Ireland to J.K.V. The post-doctoralFellowship of O.E.K. during 1999?2000 was funded by the
PRF No. 33221-AC7 administered by the ACS. | en |
| dc.format.extent | 4634 | en |
| dc.format.extent | 4642 | en |
| dc.language.iso | en | en |
| dc.publisher | American Institute of Physics | en |
| dc.relation.ispartofseries | Journal of Chemical Physics; | |
| dc.relation.ispartofseries | 114; | |
| dc.relation.ispartofseries | 10; | |
| dc.rights | Y | en |
| dc.subject | Condensed matter physics | en |
| dc.subject | dielectric relaxation | en |
| dc.title | Effects of induced steric hindrance on the dielectric behavior and H bonding in the supercooled liquid and vitreous alcohol | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/jvij | |
| dc.identifier.rssinternalid | 24382 | |
| dc.identifier.rssuri | http://dx.doi.org/10.1063/1.1346635 | en |
| dc.contributor.sponsor | Enterprise Ireland | en |
| dc.identifier.uri | http://hdl.handle.net/2262/40540 | |
