| dc.contributor.author | CONNON, STEPHEN | en |
| dc.date.accessioned | 2011-02-15T16:28:35Z | |
| dc.date.available | 2011-02-15T16:28:35Z | |
| dc.date.issued | 2009 | en |
| dc.date.submitted | 2009 | en |
| dc.identifier.citation | S. E. O Toole and S. J. Connon, The enantioselective benzoin condensation promoted by chiral triazolium precatalysts: stereochemical control via hydrogen bonding., Organic Biomolecular Chemistry, 7, 17, 2009, 3584-3593 | en |
| dc.identifier.other | Y | en |
| dc.description | PUBLISHED | en |
| dc.description | PMID: 19675916 | en |
| dc.description.abstract | The design of a new class of triazolium ion precatalysts incorporating protic substituents is described.
These materials promote the enantioselective benzoin condensation of a range of aromatic aldehydes
(1?62% ee). Catalyst evaluation studies strongly support the involvement of hydrogen bond donation by
the catalyst in the stereocentre-forming step of the catalytic cycle. | en |
| dc.description.sponsorship | Financial support from Science Foundation Ireland (SFI) and
Trinity College is gratefully acknowledged. | en |
| dc.format.extent | 3584-3593 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Organic Biomolecular Chemistry | en |
| dc.relation.ispartofseries | 7 | en |
| dc.relation.ispartofseries | 17 | en |
| dc.rights | Y | en |
| dc.subject | Organic chemistry | en |
| dc.subject | hydrogen bonding | en |
| dc.title | The enantioselective benzoin condensation promoted by chiral triazolium precatalysts: stereochemical control via hydrogen bonding. | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/connons | en |
| dc.identifier.rssinternalid | 71072 | en |
| dc.subject.TCDTheme | Nanoscience & Materials | en |
| dc.identifier.rssuri | http://dx.doi.org/10.1039/B908517C | en |
| dc.contributor.sponsor | Science Foundation Ireland (SFI) | en |
| dc.identifier.uri | http://hdl.handle.net/2262/50583 | |
