dc.contributor.author | CONNON, STEPHEN | |
dc.contributor.author | MC CABE, THOMAS | |
dc.contributor.author | WATSON, GRAEME WILLIAM | |
dc.date.accessioned | 2011-03-01T16:12:11Z | |
dc.date.available | 2011-03-01T16:12:11Z | |
dc.date.issued | 2006 | |
dc.date.submitted | 2006 | en |
dc.identifier.citation | Ciaran O. Dalaigh, Stephen J. Hynes, John E. O'Brien, Thomas McCabe, Declan J. Maher, Graeme W. Watson and Stephen J. Connon, Asymmetric acyl-transfer promoted by readily assembled chiral 4-N,N-dialkylaminopyridine derivatives , Organic and Biomolecular Chemistry, 4, 14, 2006, 2785-2793 | en |
dc.identifier.other | Y | |
dc.description | PUBLISHED | en |
dc.description.abstract | The development of a new class of chiral 4-N,N-dialkylaminopyridine acyl-transfer catalysts capable of exploiting both van der Waals (?) and H-bonding interactions to allow remote chiral information to stereochemically control the kinetic resolution of sec-alcohols with moderate to excellent selectivity (s = 6?30). Catalysts derived from (S)-?,?-diarylprolinol are considerably superior to analogues devoid of a tertiary hydroxyl moiety and possess high activity and selectivity across a broad range of substrates. | en |
dc.format.extent | 2785-2793 | en |
dc.language.iso | en | en |
dc.publisher | Royal Society of Chemistry | en |
dc.relation.ispartofseries | Organic and Biomolecular Chemistry; | |
dc.relation.ispartofseries | 4; | |
dc.relation.ispartofseries | 14; | |
dc.rights | Y | en |
dc.subject | Biochemistry | en |
dc.subject | Catalysts | en |
dc.title | Asymmetric acyl-transfer promoted by readily assembled chiral 4-N,N-dialkylaminopyridine derivatives | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/connons | |
dc.identifier.peoplefinderurl | http://people.tcd.ie/tmccabe | |
dc.identifier.peoplefinderurl | http://people.tcd.ie/watsong | |
dc.identifier.rssinternalid | 49242 | |
dc.identifier.rssuri | http://www.rsc.org/ej/OB/2006/b604632k.pdf | en |
dc.identifier.uri | http://hdl.handle.net/2262/52930 | |