Synthesis and strong optical limiting response of graphite oxide covalently functionalized with gallium phthalocyanine

Abstract

A soluble graphite oxide (GO) axially substituted gallium phthalocyanine (PcGa) hybrid material (GO?PcGa) was for the first time synthesized by the reaction of tBu4PcGaCl with GO in anhydrous DMSO at 110 ?C in the presence of K2CO3. The formation of a Ga?O bond between PcGa and GO has been confirmed by x-ray photoelectron spectroscopy. In contrast to GO, the D and G bands of GO?PcGa in the Raman spectrum are shifted to the lower wavenumbers by ?? = 11 and 18 cm ? 1, respectively. At the same level of concentration of 0.1 g l ? 1, GO?PcGa exhibit much larger nonlinear optical extinction coefficients and strong optical limiting performance than GO, tBu4PcGaCl and C60 at both 532 and 1064 nm, implying a remarkable accumulation effect as a result of the covalent link between GO and PcGa. GO?PcGa possesses three main mechanisms for the nonlinear optical response?nonlinear light scattering, two-photon absorption and reverse saturable absorption for the 532 nm pulses and nonlinear light scattering for the 1064 nm pulses. tBu4PcGaCl does not make any significant contribution to the optical limiting at 1064 nm, while GO?PcGa has a much greater optical limiting response than GO at this wavelength, this suggesting that the PcGa moiety could certainly play an unknown but important role in the GO?PcGa material system.