| dc.contributor.author | CONNON, STEPHEN | en |
| dc.date.accessioned | 2011-06-01T11:33:18Z | |
| dc.date.available | 2011-06-01T11:33:18Z | |
| dc.date.issued | 2010 | en |
| dc.date.submitted | 2010 | en |
| dc.identifier.citation | L. Cronin, F.Manoni, C. J. O' Connor and S.J. Connon*, Tunable bromomagnesium thiolate Tishchenko reaction catalysts: efficient intermolecular aldehyde-trifluoromethylketone coupling, Angewandte Chemie International Edition, 49, 17, 2010, 3045-3048 | en |
| dc.identifier.other | Y | en |
| dc.description | PUBLISHED | en |
| dc.description | Highlighted in Synfacts (2010, 817). | en |
| dc.description.abstract | A new thiolate-catalyzed Tishchenko reaction inspired by biochemical processes features exceptionally good control over the catalyst's steric/electronic properties. The isolation of reaction intermediates provided valuable insights into the reaction mechanism, which in turn has allowed the development of the first cross-Tishchenko coupling reactions between aldehydes and activated ketones | en |
| dc.description.sponsorship | Financial support from the European Research Council (ERC) and
Science Foundation Ireland (SFI) is gratefully acknowledged | en |
| dc.format.extent | 3045-3048 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Angewandte Chemie International Edition | en |
| dc.relation.ispartofseries | 49 | en |
| dc.relation.ispartofseries | 17 | en |
| dc.rights | Y | en |
| dc.subject | Biochemistry | en |
| dc.subject | disproportionation | en |
| dc.subject | Grignard reagents | en |
| dc.subject | homogeneous catalysis | en |
| dc.subject | synthetic methods | en |
| dc.subject | Tishchenko reaction | en |
| dc.title | Tunable bromomagnesium thiolate Tishchenko reaction catalysts: efficient intermolecular aldehyde-trifluoromethylketone coupling | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/connons | en |
| dc.identifier.rssinternalid | 71055 | en |
| dc.subject.TCDTheme | Nanoscience & Materials | en |
| dc.identifier.rssuri | http://dx.doi.org/10.1002/anie.200907167 | en |
| dc.contributor.sponsor | Science Foundation Ireland (SFI) | en |
| dc.identifier.uri | http://hdl.handle.net/2262/56215 | |
