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{4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate

dc.contributor.authorMCCABE, THOMASen
dc.contributor.authorSCHMITT, WOLFGANGen
dc.contributor.authorMARZEC, BARTOSZen
dc.date.accessioned2011-11-18T17:13:42Z
dc.date.available2011-11-18T17:13:42Z
dc.date.issued2011en
dc.date.submitted2011en
dc.identifier.citationMarzec B, Mariyatra MB, McCabe T, Schmitt W, {4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrate, Acta crystallographica. Section E, Structure reports online, 67, Pt 8, 2011, m1073-m1074en
dc.identifier.issn1600-5368en
dc.identifier.otherYen
dc.descriptionPUBLISHEDen
dc.description.abstractThe title compound, [CuCl2(C18H18N8)]?2CH3OH?H2O, contains a pentacoordinated Cu(II) atom bonded to the tridentate 4,6-bis[(E)-1-methyl-2-(pyridin-2-ylmethylidene)hydrazinyl]pyrimidine ligand and two Cl atoms. The geometry around the CuII atom is distorted square-pyramidal. The molecules pack in the crystal structure via O-HCl, O-HN, C-HCl and C-HO hydrogen bonds, C-H and - interactions [centroid-centroid distances of the pyrimidine-pyridine and pyridine-pyridine interactions are 3.750 (3) and 3.850 (3) ?, respectively], forming sheet-like assemblies.en
dc.description.sponsorshipThe authors thank the Science Foundation Ireland for ?nancial support (SFI; 06/RFP/CHE174 and 08/IN.1/I2047). Financial support from DRHEA (BM) and Trinity College is gratefully acknowledged.en
dc.format.extentm1073-m1074en
dc.language.isoenen
dc.relation.ispartofseriesActa crystallographica. Section E, Structure reports onlineen
dc.relation.ispartofseries67en
dc.relation.ispartofseriesPt 8en
dc.rightsYen
dc.subjectChemistryen
dc.subjectCrystallographyen
dc.title{4,6-Bis[(E)-1-methyl-2-(pyridin-2-yl-methyl-idene-κN)hydrazinyl-κN]pyrimidine-κN}dichloridocopper(II) methanol disolvate monohydrateen
dc.typeJournal Articleen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/tmccabeen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/schmittwen
dc.identifier.rssinternalid75959en
dc.identifier.doihttp://dx.doi.org/10.1107/S1600536811025414en
dc.subject.TCDThemeNanoscience & Materialsen
dc.identifier.rssurihttp://dx.doi.org/10.1107/S1600536811025414en
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.contributor.sponsorGrantNumber08/IN.1/I2047en
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.contributor.sponsorGrantNumber06/RFP/CHE174en
dc.identifier.urihttp://hdl.handle.net/2262/60824


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