| dc.contributor.author | SENGE, MATHIAS | en |
| dc.date.issued | 2010 | en |
| dc.date.submitted | 2010 | en |
| dc.identifier.citation | Davis, M.; Senge, M. O.; Locos, O. B., Anthracenylporphyrins, Zeitschrift fuer Naturforschung, 65b, 2010, 1472 - 1484 | en |
| dc.identifier.other | Y | en |
| dc.description | PUBLISHED | en |
| dc.description.abstract | We report the synthesis and characterization of meso-anthracenylporphyrins with zinc
and nickel metal centers. A variety of novel aryl and alky meso substituted
anthracenylporphyrins were synthesized via step-wise Suzuki cross-coupling reactions using
anthracenyl boronates. This method was compared to standard syntheses based on
condensation reactions to yield anthracenylporphyrins of the A2B2- and A3B-type. This was
complemented by the synthesis of a number of the functionalized anthracene derivatives via
Suzuki couplings for use in porphyrin functionalization. Selected systems were subjected to
single-crystal X-ray analysis which revealed an unusual close packing for nickel(II)
anthracenylporphyrins. | en |
| dc.description.sponsorship | This work was supported by a grant from Science Foundation Ireland (SFI P.I.
09/IN.1/B2650). We are indebted to Dr. T. McCabe for some of the X-ray data
collections. | en |
| dc.format.extent | 1472 | en |
| dc.format.extent | 1484 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Zeitschrift fuer Naturforschung | en |
| dc.relation.ispartofseries | 65b | en |
| dc.rights | Y | en |
| dc.subject.other | porphyrins | |
| dc.title | Anthracenylporphyrins | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/sengem | en |
| dc.identifier.rssinternalid | 71030 | en |
| dc.rights.ecaccessrights | OpenAccess | |
| dc.contributor.sponsor | Science Foundation Ireland (SFI) | en |
| dc.contributor.sponsorGrantNumber | 09/IN.1/B2650 | en |
| dc.identifier.uri | http://hdl.handle.net/2262/67505 | |
