| dc.contributor.author | LYONS, MICHAEL | en |
| dc.contributor.author | GODWIN, IAN | en |
| dc.date.accessioned | 2013-11-04T16:25:53Z | |
| dc.date.available | 2013-11-04T16:25:53Z | |
| dc.date.created | 12-16 May 2013 | en |
| dc.date.issued | 2013 | en |
| dc.date.submitted | 2013 | en |
| dc.identifier.citation | Ian J Godwin, Michael E.G. Lyons, Dimensionally Stable Anodes (DSA) for Electrochemical Water Splitting: Redox Properties, OER Kinetics and Mechanism at RuO2/NiO modified electrodes in aqueous base, ECS Transactions, 223rd ECS Spring Meeting, Toronto, ON, Canada, 12-16 May 2013, 53, 23, Electrochemical Society, 2013, 21 - 31 | en |
| dc.identifier.other | Y | en |
| dc.description | PUBLISHED | en |
| dc.description | Toronto, ON, Canada | en |
| dc.description.abstract | The RuO2/NiO electrode was found to be extremely effective as a
water oxidation catalyst in alkaline conditions. Addition of 25
mol % of RuO2 to a NiO electrode lowered the oxygen evolution
reaction (OER) overpotential by ca. 30 %. Based on kinetic data
obtained we have proposed a mechanism for both RuO2 and NiO
utilizing the surfaquo group concept which envisages water
oxidation occurring at hydrated interlinked oxy-metal surface
active groups. | en |
| dc.description.sponsorship | SFI/10/IN.1/I2969 | en |
| dc.format.extent | 21 | en |
| dc.format.extent | 31 | en |
| dc.language.iso | en | en |
| dc.publisher | Electrochemical Society | en |
| dc.relation.ispartofseries | 53 | en |
| dc.relation.ispartofseries | 23 | en |
| dc.rights | Y | en |
| dc.subject | Oxygen evolution | en |
| dc.subject | Ruthenium/Nickel mixed oxides | en |
| dc.title | Dimensionally Stable Anodes (DSA) for Electrochemical Water Splitting: Redox Properties, OER Kinetics and Mechanism at RuO2/NiO modified electrodes in aqueous base | en |
| dc.title.alternative | ECS Transactions | en |
| dc.title.alternative | 223rd ECS Spring Meeting | en |
| dc.type | Conference Paper | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/melyons | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/igodwin | en |
| dc.identifier.rssinternalid | 87182 | en |
| dc.rights.ecaccessrights | OpenAccess | |
| dc.subject.TCDTheme | Nanoscience & Materials | en |
| dc.subject.TCDTheme | Smart & Sustainable Planet | en |
| dc.identifier.rssuri | http://ecst.ecsdl.org/content/53/23/21.full.pdf+html | en |
| dc.identifier.orcid_id | 0000-0002-0320-7547 | en |
| dc.contributor.sponsor | Science Foundation Ireland (SFI) | en |
| dc.contributor.sponsorGrantNumber | SFI/10/IN.1/I2969 | en |
| dc.identifier.uri | http://hdl.handle.net/2262/67561 | |
