Homologous size-extension of hybrid vanadate capsules - Solid state structures, solution stability and surface deposition
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2014Access:
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Mahimaidoss, M.B., Krasnikov, S.A., Reck, L., (...), Shvets, I.V., Schmitt, W., Homologous size-extension of hybrid vanadate capsules - Solid state structures, solution stability and surface deposition, Chemical Communications, 50, 18, 2014, 2265-2267Download Item:
Abstract:
The dimensions and cavity sizes of the molecular capsules with the general formula [V10O18L4]10- can be controlled modularly through the nature of the bifunctional, rigid organophosphonate ligands L1 and L2 (L1 = bis(4-phosphonatophenyl)ethyne and L2 = bis(4-phosphonatophenyl) butadiyne); the solution stability of the molecular entities as demonstrated by ESI-MS studies permits their assembly on the Au(111) surface on a sub-monolayer scale giving rise to a 2D supramolecular structure that is comparable to the packing arrangements of the capsules in the crystal structures.
Sponsor
Grant Number
Science Foundation Ireland (SFI)
08/IN.1/I2047
Science Foundation Ireland (SFI)
06/RFP/CHE173
Author's Homepage:
http://people.tcd.ie/ivchvetshttp://people.tcd.ie/schmittw
http://people.tcd.ie/zhun
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Science Foundation Ireland (SFI)Science Foundation Ireland (SFI)
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Chemical Communications50
18
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PhysicsDOI:
http://dx.doi.org/10.1039/c3cc48541bMetadata
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