| dc.contributor.author | BAKER, ROBERT | en |
| dc.date.accessioned | 2014-06-03T13:06:27Z | |
| dc.date.available | 2014-06-03T13:06:27Z | |
| dc.date.issued | 2002 | en |
| dc.date.submitted | 2002 | en |
| dc.identifier.citation | R.J. Baker, P.G. Edwards J.Gracia-Moria, F. Ingold and K.M.A. Malik, Manganese and Rhenium triphosphorus macrocycle complexes and reactions with alkenes., J. Chem. Soc., Dalton Trans, 2002, 3985, 3992 | en |
| dc.identifier.other | Y | en |
| dc.description | PUBLISHED | en |
| dc.description.abstract | The synthesis of Re(III), Re(I) and Mn(I) compounds of the macrocyclic phosphine ligand 1,5,9-trialkyl-1,5,9-triphosphacyclododecane, 12[ane]P3R3 (R = Et, iBu) is described. The reaction of 12[ane]P3R3 with ReCl3(PPh3)2(CH3CN) or ReCl3(PPhMe2)3 gives rise to the octahedral d4 complexes (12[ane]P3R3)ReCl3 (1R). Reduction of 1iBu with Na/Hg under a CO atmosphere gives the rhenium(I) compound (12[ane]P3R3)Re(CO)2Cl, 2R which undergoes further reactivity to give hydride (3R), vinylidene (4R) and allenylidene (5R) compounds. With Mn(CO)5Br, 12[ane]P3Et3 gives the octahedral d6 complex, (12[ane]P3Et3)Mn(CO)2Br, 6Et. The crystal structures of (12[ane]P3iBu3)ReCl3 and (12[ane]P3Et3)Mn(CO)2Br are presented. | en |
| dc.format.extent | 3985 | en |
| dc.format.extent | 3992 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | J. Chem. Soc., Dalton Trans | en |
| dc.rights | Y | en |
| dc.subject | Chemistry | en |
| dc.title | Manganese and Rhenium triphosphorus macrocycle complexes and reactions with alkenes. | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/bakerrj | en |
| dc.identifier.rssinternalid | 57397 | en |
| dc.identifier.doi | http://dx.doi.org/10.1039/b205754a | en |
| dc.rights.ecaccessrights | openAccess | |
| dc.identifier.uri | http://hdl.handle.net/2262/69575 | |
