dc.contributor.author | SCHMITT, WOLFGANG | en |
dc.date.accessioned | 2014-11-24T16:31:34Z | |
dc.date.available | 2014-11-24T16:31:34Z | |
dc.date.issued | 2005 | en |
dc.date.submitted | 2005 | en |
dc.identifier.citation | W. Schmitt, C. E. Anson, W. Wernsdorfer, A. K. Powell, Formal encapsulation of [Fe(H2O)6]3+ by dinuclear {Fe2(hpdta)} units leads to a nonanuclear S = 13/2 Fe(III) oxo-cluster showing magnetic hysteresis, Chemical Communications, 2005, 2098, 2100 | en |
dc.identifier.other | Y | en |
dc.description | PUBLISHED | en |
dc.description.abstract | Under solvothermal conditions the unprecedented nonanuclear Fe(III) aggregate [Fe9(mu3-O)4(mu-OH)4(hpdta)4]5- is formed through the formal encapsulation of [Fe(H2O)6]3+ by four [Fe2(hpdta)(H2O)2]+ units: the aggregates have ground state spins of S= 13/2 while the observed hysteresis below 1.8 K results from inter-cluster antiferromagnetic coupling. | en |
dc.format.extent | 2098 | en |
dc.format.extent | 2100 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Chemical Communications | en |
dc.rights | Y | en |
dc.subject | Chemistry | en |
dc.title | Formal encapsulation of [Fe(H2O)6]3+ by dinuclear {Fe2(hpdta)} units leads to a nonanuclear S = 13/2 Fe(III) oxo-cluster showing magnetic hysteresis | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/schmittw | en |
dc.identifier.rssinternalid | 30135 | en |
dc.identifier.doi | http://dx.doi.org/10.1039/b416766j | en |
dc.rights.ecaccessrights | openAccess | |
dc.identifier.rssuri | http://www.rsc.org/ej/CC/2005/b416766j.pdf | en |
dc.identifier.uri | http://hdl.handle.net/2262/72171 | |