Turbulence-assisted shear exfoliation of graphene using household detergent and a kitchen blender
Citation:
Varrla, E. Paton, K.R. Backes, C. Harvey, A. Smith, R.J. McCauley, J. Coleman, J.N., Turbulence-assisted shear exfoliation of graphene using household detergent and a kitchen blender, Nanoscale, 6, 20, 2014, 11810 - 11819Download Item:
Abstract:
To facilitate progression from the lab to commercial applications, it will be necessary to develop simple, scalable methods to produce high quality graphene. Here we demonstrate the production of large quantities of defect-free graphene using a kitchen blender and household detergent. We have characterised the scaling of both graphene concentration and production rate with the mixing parameters: mixing time, initial graphite concentration, rotor speed and liquid volume. We find the production rate to be invariant with mixing time and to increase strongly with mixing volume, results which are important for scale-up. Even in this simple system, concentrations of up to 1 mg ml−1 and graphene masses of >500 mg can be achieved after a few hours mixing. The maximum production rate was [similar]0.15 g h−1, much higher than for standard sonication-based exfoliation methods. We demonstrate that graphene production occurs because the mean turbulent shear rate in the blender exceeds the critical shear rate for exfoliation.
Sponsor
Grant Number
Science Foundation Ireland (SFI)
11/PI/1087.
Author's Homepage:
http://people.tcd.ie/colemajDescription:
PUBLISHED
Author: COLEMAN, JONATHAN
Sponsor:
Science Foundation Ireland (SFI)Type of material:
Journal ArticleCollections
Series/Report no:
Nanoscale6
20
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Full text availableKeywords:
lab to commercial applicationsDOI:
http://dx.doi.org/10.1039/c4nr03560gMetadata
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