| dc.contributor.author | SENGE, MATHIAS | en |
| dc.date.accessioned | 2015-05-06T10:27:53Z | |
| dc.date.available | 2015-05-06T10:27:53Z | |
| dc.date.issued | 2014 | en |
| dc.date.submitted | 2014 | en |
| dc.identifier.citation | Senge, M. O.; Zawadzka, M., Structural investigation of 5,10-A2B2-type porphyrins Palladium(II) and zinc(II) complexes of 5,10-dibromo-15,20-bis(4-methylphenyl)porphyrin., Acta Crystallographica, C70, 2014, 1143 1146 | en |
| dc.identifier.other | Y | en |
| dc.description | PUBLISHED | en |
| dc.description.abstract | The analysis of [5,10-dibromo-15,20-bis(4-methylphenyl)por-
phyrinato]palladium(II), [Pd(C
34
H
22
Br
2
N
4
)], and [5,10-di-
bromo-15,20-bis(4-methylphenyl)porphyrinato](methanol)-
zinc(II), [Zn(C
34
H
22
Br
2
N
4
)(CH
4
O)], reveals a small but
localized influence of the bromine residues on the conforma-
tion of the macrocycle. A comparison of the 5,10-dibromo
substituent pattern with literature data for 5,15-dibromo-
porphyrins shows similar in-plane distortions in both but a
different mix of out-of-plane distortion modes for the
different regiochemical arrangements. | en |
| dc.description.sponsorship | This work was supported by a grant from Science Founda-
tion Ireland (SFI P.I. 09/IN.1/B2650). | en |
| dc.format.extent | 1143 1146 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Acta Crystallographica | en |
| dc.relation.ispartofseries | C70 | en |
| dc.rights | Y | en |
| dc.subject | crystal structure; 5,10-dibromo-15,20-bis(4- methylphenyl)porphyrin; palladium(II) complex; zinc(II) complex; coordination chemistry; 5,15-disubstitution pattern; normal structural decomposition (NSD) method; 5,10- A 2 B 2 -type porphyrins | en |
| dc.subject.lcsh | crystal structure; 5,10-dibromo-15,20-bis(4- methylphenyl)porphyrin; palladium(II) complex; zinc(II) complex; coordination chemistry; 5,15-disubstitution pattern; normal structural decomposition (NSD) method; 5,10- A 2 B 2 -type porphyrins | en |
| dc.title | Structural investigation of 5,10-A2B2-type porphyrins Palladium(II) and zinc(II) complexes of 5,10-dibromo-15,20-bis(4-methylphenyl)porphyrin. | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/sengem | en |
| dc.identifier.rssinternalid | 99897 | en |
| dc.identifier.doi | http://dx.doi.org/10.1107/S2053229614023687 | en |
| dc.rights.ecaccessrights | openAccess | |
| dc.contributor.sponsor | Science Foundation Ireland (SFI) | en |
| dc.contributor.sponsorGrantNumber | SFI P.I. 09/IN.1/B2650 | en |
| dc.identifier.uri | http://hdl.handle.net/2262/73846 | |
