| dc.contributor.author | Baker, Robert | en |
| dc.contributor.author | Browne, Michelle | en |
| dc.date.accessioned | 2017-01-12T12:44:26Z | |
| dc.date.available | 2017-01-12T12:44:26Z | |
| dc.date.issued | 2016 | en |
| dc.date.submitted | 2016 | en |
| dc.identifier.citation | S. Nuzzo, M. P. Browne, B. Twamley, M. E. G. Lyons and R. J. Baker, A structural and spectroscopic study of the first uranyl selenocyanate, [Et4N]3[UO2(NCSe)5], Inorganics, 4, 2016, 4 - 8 | en |
| dc.identifier.other | Y | en |
| dc.description | PUBLISHED | en |
| dc.description.abstract | he first example of a uranyl selenocyanate compound is reported. The compound [Et4N]3[UO2(NCSe)5] has been synthesized and fully characterized by vibrational and multinuclear (1H, 13C{1H} and 77Se{1H}) NMR spectroscopy. The photophysical properties have also been recorded and trends in a series of uranyl pseudohalides discussed. Spectroscopic evidence shows that the U–NCSe bonding is principally ionic. An electrochemical study revealed that the reduced uranyl(V) species is unstable to disproportionation and a ligand based oxidation is also observed. The structure of [Et4N]4[UO2(NCSe)5][NCSe] is also presented and Se···H–C hydrogen bonding and Se···Se chalcogen–chalcogen interactions are seen | en |
| dc.description.sponsorship | We thank Trinity College Dublin for funding this work. | en |
| dc.format.extent | 4 | en |
| dc.format.extent | 8 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Inorganics | en |
| dc.relation.ispartofseries | 4 | en |
| dc.rights | Y | en |
| dc.subject | uranyl; structural determination; photophysics | en |
| dc.subject.lcsh | uranyl; structural determination; photophysics | en |
| dc.title | A structural and spectroscopic study of the first uranyl selenocyanate, [Et4N]3[UO2(NCSe)5] | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/bakerrj | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/mbrowne2 | en |
| dc.identifier.rssinternalid | 122819 | en |
| dc.identifier.doi | http://dx.doi.org/10.3390/inorganics4010004 | en |
| dc.rights.ecaccessrights | openAccess | |
| dc.identifier.rssuri | http://www.mdpi.com/2304-6740/4/1/4 | en |
| dc.identifier.orcid_id | 0000-0003-1416-8659 | en |
| dc.identifier.uri | http://hdl.handle.net/2262/78695 | |
