Structural variation in cation-assisted assembly of high-nuclearity Mn arsonate and phosphonate wheels
![Thumbnail](/themes/edepositireland/images/white_rectangle.jpeg)
File Type:
UnknownItem Type:
Journal ArticleDate:
2016Access:
openAccessCitation:
Chimamkpam T.O, Clérac R, Mitcov D, Twamley B, Venkatesan M, Schmitt W, Structural variation in cation-assisted assembly of high-nuclearity Mn arsonate and phosphonate wheels, Dalton Transactions, 45, 4, 2016, 1349 - 1353Abstract:
Comproportionation reactions between MnCl2 and KMnO4 in the presence of arsonate or phosphonate ligands promote the cation-assisted assembly of high-nuclearity, wheel-shaped or toroidal {Mn8} (1) and {Mn24} (2) complexes; the closely corresponding reaction systems provide insights into the complexation behaviour of homologous phosphonate/arsonate ligand species.
Sponsor
Grant Number
Science Foundation Ireland (SFI)
SFI, 13/IA/1896
Science Foundation Ireland (SFI)
08/IN.1/I2047
Author's Homepage:
http://people.tcd.ie/schmittwhttp://people.tcd.ie/venkatem
Description:
PUBLISHEDCited By :2 Export Date: 13 December 2016
Author: Schmitt, Wolfgang; Venkatesan, Munuswamy
Sponsor:
Science Foundation Ireland (SFI)Science Foundation Ireland (SFI)
Type of material:
Journal ArticleCollections
Series/Report no:
Dalton Transactions45
4
Availability:
Full text availableKeywords:
MnCl2 and KMnO4DOI:
http://dx.doi.org/10.1039/c5dt04820fMetadata
Show full item recordLicences: