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Norbornene chaotropic salts as low molecular mass ionic organogelators (LMIOGs)

dc.contributor.authorGunnlaugsson, Thorfinnur
dc.contributor.authorEngstrom, Jordan R.
dc.contributor.authorSavyasachi, Aramballi J.
dc.contributor.authorParhizkar, Marzieh
dc.contributor.authorSutti, Alessandra
dc.contributor.authorHawes, Chris S.
dc.contributor.authorWhite, Jonathan M.
dc.contributor.authorPfeffer, Frederick M.
dc.date.accessioned2019-09-23T12:36:21Z
dc.date.available2019-09-23T12:36:21Z
dc.date.issued2018
dc.date.submitted2018en
dc.identifier.citationEngstrom, J.R. and Savyasachi, A.J. and Parhizkar, M. and Sutti, A. and Hawes, C.S. and White, J.M. and Gunnlaugsson, T. and Pfeffer, F.M., Norbornene chaotropic salts as low molecular mass ionic organogelators (LMIOGs), Chemical Science, 9, 23, 2018, 5233-5241en
dc.identifier.otherY
dc.description.abstractPhenylalanine functionalised norbornene (9:Na) functions as a potent, low molecular-mass (MW = 333 Da) ionic organogelator with a minimum gelating concentration of 0.5 wt% in THF, i-PrOH, 1,4-dioxane and n-BuOH. Fibrous crystals form in the gel and X-ray crystallography identified a cation mediated helical assembly process controlled by the chirality of the phenylalanine. In addition to excellent gelating properties 9:Na readily forms aqueous biphasic and triphasic systems.en
dc.format.extent5233-5241en
dc.language.isoenen
dc.relation.ispartofseriesChemical Science;
dc.relation.ispartofseries9;
dc.relation.ispartofseries23;
dc.rightsYen
dc.subjectorganogelating agentsen
dc.subjectLow molecular mass ionic organogelatorsen
dc.subjectOrganogelsen
dc.titleNorbornene chaotropic salts as low molecular mass ionic organogelators (LMIOGs)en
dc.typeJournal Articleen
dc.type.supercollectionscholarly_publicationsen
dc.type.supercollectionrefereed_publicationsen
dc.identifier.peoplefinderurlhttp://people.tcd.ie/gunnlaut
dc.identifier.rssinternalid197616
dc.identifier.doihttp://dx.doi.org/10.1039/c8sc01798k
dc.rights.ecaccessrightsopenAccess
dc.identifier.orcid_id0000-0003-4814-6853
dc.contributor.sponsorScience Foundation Ireland (SFI)en
dc.contributor.sponsorGrantNumber13/IA/1865en
dc.identifier.urihttps://pubs.rsc.org/en/content/articlelanding/2018/sc/c8sc01798k#!divAbstract
dc.identifier.urihttp://hdl.handle.net/2262/89533


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