dc.contributor.author | Bradley, Louise | |
dc.date.accessioned | 2020-07-30T07:15:44Z | |
dc.date.available | 2020-07-30T07:15:44Z | |
dc.date.issued | 2007 | |
dc.date.submitted | 2007 | en |
dc.identifier.citation | Lucas, F. O., Mitra, A., McNally, P.J., Daniels, S., Bradley, A.L., Taylor, D.M., Proskuryakov, Y.Y., Durose, K., Cameron, D.C., Evaluation of the chemical, electronic and optoelectronic properties of γ-CuCl thin films and their fabrication on Si substrates, Journal of Physics D: Applied Physics, 2007, 40, 11, 3461 - 3467 | en |
dc.identifier.other | Y | |
dc.description | PUBLISHED | en |
dc.description.abstract | CuCl is a I–VII semiconductor material with a direct band gap of ~3.4 eV. It exhibits a zincblende structure (γ-phase) at low temperatures, up to ~680 K. Unlike GaN, ZnO and related materials, CuCl has a relatively low lattice mismatch with Si (<0.4%) and a large excitonic binding energy (~190 meV). This suggests the possibility of the fabrication of excitonic-based blue/UV optoelectronic devices on Si with relatively low threading dislocation densities. In this study, CuCl has been deposited and examined as a candidate material for the fabrication of these devices. X-ray diffraction (XRD) measurements confirmed that the deposited films were preferentially oriented in the (1 1 1) plane. Room temperature photoluminescence measurements reveal a strong Z3 free exciton peak (3.232 eV). Both steady state dc and ac impedance spectroscopy experiments suggested that the deposited CuCl is a mixed ionic–electronic semiconductor material. An electronic conductivity of the order of 2.3 × 10−7 S cm−1 was deduced to be in coexistence with Cu+ ionic conductivity using irreversible electrodes (Au), while a total conductivity of the order of 6.5 × 10−7 S cm−1 was obtained using reversible electrodes (Cu) at room temperature. Further to this, we have identified some of the challenges in fabricating an optoelectronic device based on a CuCl/Si hybrid platform and propose some possible solutions. | en |
dc.format.extent | 3461 | en |
dc.format.extent | 3467 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Journal of Physics D-Applied Physics; | |
dc.relation.ispartofseries | 40; | |
dc.relation.ispartofseries | 11; | |
dc.rights | Y | en |
dc.subject | Optoelectronic device | en |
dc.title | Evaluation of the chemical, electronic and optoelectronic properties of γ-CuCl thin films and their fabrication on Si substrates | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/bradlel | |
dc.identifier.rssinternalid | 49456 | |
dc.identifier.doi | http://dx.doi.org/10.1088/0022-3727/40/11/030 | |
dc.rights.ecaccessrights | openAccess | |
dc.identifier.rssuri | http://www.iop.org/EJ/article/0022-3727/40/11/030/d7_11_030.pdf | |
dc.identifier.orcid_id | 0000-0002-9399-8628 | |
dc.identifier.uri | http://hdl.handle.net/2262/93078 | |