dc.contributor.author | Garcia Melchor, Max | en |
dc.contributor.author | Schmitt, Wolfgang | en |
dc.date.accessioned | 2020-10-05T12:39:03Z | |
dc.date.available | 2020-10-05T12:39:03Z | |
dc.date.issued | 2020 | en |
dc.date.submitted | 2020 | en |
dc.identifier.citation | Ako, A. M.; Kathalikkattil, A. C.; Elliott, R.; Soriano-López, J.; McKeogh, I. M.; Zubair, M.; Twamley, B.; Zhu, N.; García-Melchor, M.; Kruger, P. E.; Schmitt, W., Synthetic approaches to metallo-supramolecular Co(II) polygons and potential use for H2O oxidation, Inorganic Chemistry, 59, 2020, 14432- | en |
dc.identifier.other | Y | en |
dc.description | PUBLISHED | en |
dc.description.abstract | Metal-directed self-assembly has been applied to prepare supramolecular coordination polygons which adopt tetrahedral (1) or trigonal disklike topologies (2). In the solid state, 2 assembles into a stable halide–metal–organic material (Hal-MOM-2), which catalyzes H2O oxidation under photo- and electrocatalytic conditions, operating with a maximum TON = 78 and TOF = 1.26 s–1. DFT calculations attribute the activity to a CoIII-oxyl species. This study provides the first account of how CoII imine based supramolecules can be employed as H2O oxidation catalysts. | en |
dc.format.extent | 14432 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Inorganic Chemistry | en |
dc.relation.ispartofseries | 59 | en |
dc.rights | Y | en |
dc.title | Synthetic approaches to metallo-supramolecular Co(II) polygons and potential use for H2O oxidation | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/garciamm | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/schmittw | en |
dc.identifier.rssinternalid | 220681 | en |
dc.identifier.doi | https://doi.org/10.1021/acs.inorgchem.0c02182 | en |
dc.rights.ecaccessrights | openAccess | |
dc.identifier.orcid_id | 0000-0003-1348-4692 | en |
dc.identifier.uri | http://hdl.handle.net/2262/93681 | |