| dc.contributor.author | McDonald, Aidan | |
| dc.date.accessioned | 2020-10-19T20:41:53Z | |
| dc.date.available | 2020-10-19T20:41:53Z | |
| dc.date.issued | 2020 | |
| dc.date.submitted | 2020 | en |
| dc.identifier.citation | Lovisari, M., McDonald, A.R., Hydrogen Atom Transfer Oxidation by a Gold-Hydroxide Complex, Inorganic Chemistry, 2020, 59, 6, 3659–3665 | en |
| dc.identifier.other | Y | |
| dc.description | PUBLISHED | en |
| dc.description.abstract | AuIII-oxygen adducts have been implicated as intermediates in homogeneous and heterogeneous Au oxidation catalysis, but their reactivity is under-explored. Complex 1, ([AuIII(OH)(terpy)](ClO4)2, (terpy = 2,2':6',2-terpyridine), readily oxidized substrates bearing C-H and O-H bonds. Kinetic analysis revealed that the oxidation occurred through a hydrogen atom transfer (HAT) mechanism. Stable radicals were detected and quantified as products of almost quantitative HAT oxidation of alcohols by 1. Our findings highlight the possible role of AuIII-oxygen adducts in oxidation catalysis and the capability of late transition metal-oxygen adducts to perform proton coupled electron transfer. | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Inorganic Chemistry; | |
| dc.rights | Y | en |
| dc.title | Hydrogen Atom Transfer Oxidation by a Gold-Hydroxide Complex | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/aimcdona | |
| dc.identifier.rssinternalid | 215364 | |
| dc.rights.ecaccessrights | openAccess | |
| dc.identifier.orcid_id | 0000-0002-8930-3256 | |
| dc.identifier.uri | http://hdl.handle.net/2262/93854 | |
