Pt and RhPt dendritic nanowires and their potential application as anodic catalysts for fuel cells

Abstract

Fuel cells have a number of benefits over conventional combustion-based technologies and can be used in a range of important applications, including transportation, as well as stationary, portable and emergency backup power systems. One of the major challenges in this field, however lies in controlling catalyst design which is critical for developing efficient and cost-effective fuel cell technology. Herein, for the first time, we report a facile controlled synthesis of Pt and RhPt dendritic nanowires using ultrathin AuAg nanowires as sacrificial templates. These dendritic nanowires exhibit remarkable catalytic performance in the elecrochemical oxidation of methanol and formic acid. In particular, the RhPt dendritic nanostructures show very high resistance to catalyst poisoning in methanol oxidation. This research demonstrates the advantages of using bimetallic dendritic nanostructures and we believe that these materials and electrocatalytic studies are important for further advancement of fuel cell research and technology.