dc.contributor.author | Gunnlaugsson, Thorfinnur | |
dc.contributor.author | Schmitt, Wolfgang | |
dc.date.accessioned | 2022-04-03T19:46:45Z | |
dc.date.available | 2022-04-03T19:46:45Z | |
dc.date.issued | 2018 | |
dc.date.submitted | 2018 | en |
dc.identifier.citation | McCarney, E.P. and Hawes, C.S. and Kitchen, J.A. and Byrne, K. and Schmitt, W. and Gunnlaugsson, T., A Lanthanide luminescent cation exchange material derived from a flexible tricarboxylic acid 2,6-Bis(1,2,3-Triazol-4-yl)pyridine (btp) tecton, Inorganic Chemistry, 2018, 57, 7, 3920-3930 | en |
dc.identifier.other | Y | |
dc.description.abstract | The synthesis of the three-dimensional metal–organic framework material, [Zn7L6]·(H2NMe2)4·(H2O)45 (1), derived from a flexible tricarboxylic acid 2,6-bis(1,2,3-triazol-4-yl)pyridine (btp) ligand, is presented. The btp ligand, H3L, adopts a three-dimensional hydrogen bonding network in the crystalline state through a combination of carboxylic acid dimer and syn–anti-btp/carboxylic acid hydrogen bonding synthons. The Zn(II) species 1 exhibits a three-dimensional framework structure with the rare crs topology and contains linear and undulated solvent channels extending in three dimensions. The guest exchange and gas adsorption properties of 1 were investigated; herein we demonstrate the exchange of dimethylammonium cations from the as-synthesized material with cationic guest molecules in the form of dyes and luminescent Ln(III) ions. Sensitization of Eu(III) and Tb(III) inside the porous network of 1 was achieved upon cation exchange, with a view toward developing functional luminescent materials. | en |
dc.format.extent | 3920-3930 | en |
dc.language.iso | en | en |
dc.relation.ispartofseries | Inorganic Chemistry; | |
dc.relation.ispartofseries | 57; | |
dc.relation.ispartofseries | 7; | |
dc.rights | Y | en |
dc.title | A Lanthanide luminescent cation exchange material derived from a flexible tricarboxylic acid 2,6-Bis(1,2,3-Triazol-4-yl)pyridine (btp) tecton | en |
dc.type | Journal Article | en |
dc.type.supercollection | scholarly_publications | en |
dc.type.supercollection | refereed_publications | en |
dc.identifier.peoplefinderurl | http://people.tcd.ie/schmittw | |
dc.identifier.peoplefinderurl | http://people.tcd.ie/gunnlaut | |
dc.identifier.rssinternalid | 186800 | |
dc.identifier.doi | http://dx.doi.org/10.1021/acs.inorgchem.8b00080 | |
dc.rights.ecaccessrights | openAccess | |
dc.identifier.uri | http://hdl.handle.net/2262/98395 | |