A cubane-type manganese complex with H2O oxidation capabilities
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2020Access:
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Tandon, Swetanshu, Soriano-López, Joaquín, Kathalikkattil, Amal C., Jin, Guanghua, Wix, Paul, Venkatesan, Munuswamy, Lundy, Ross, Morris, Michael A., Watson, Graeme W., Schmitt, Wolfgang, A cubane-type manganese complex with H2O oxidation capabilities, Sustainable Energy & Fuels, 2020, 4, 9, 4464 - 4468Download Item:
Abstract:
We report the synthesis and characterisation of [Mn8K2O4(OH)2((CH3)3CCOO)16(CH3CN)2] whose cluster core shares some features with the oxygen evolving complex (OEC), the natural water oxidation catalyst. Importantly, this complex provides a bio-inspired complex that promotes catalytic H2O oxidation at neutral pH value.
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http://people.tcd.ie/schmittwhttp://people.tcd.ie/watsong
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Sustainable Energy & Fuels;4;
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http://dx.doi.org/10.1039/D0SE00701CISSN:
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