Dramatic mechanistic switch in Sn/AuI group exchanges: Transmetalation vs. oxidative addition

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Journal Article
Date:
2016
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Carrasco, D.; García-Melchor, M.; Casares, J. A.; Espinet, P., Dramatic mechanistic switch in Sn/AuI group exchanges: Transmetalation vs. oxidative addition, Chemical Communications, 52, 23, 2016, 4305 - 4308
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Abstract:
The mechanism of Ph/X exchange in reactions involving SnPh(n)Bu3 and [AuXL] complexes switches dramatically from the usual concerted mechanism involving Ar/X mixed bridges when X = Cl, to an unexpected oxidative addition/reductive elimination pathway via an Au(III) intermediate when X = vinyl.
URI:
http://hdl.handle.net/2262/89251
Author's Homepage:
http://people.tcd.ie/garciamm
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PUBLISHED
Author: Garcia Melchor, Max
Type of material:
Journal Article
URI:
http://hdl.handle.net/2262/89251
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Chemical Communications
52
23
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Subject:
Transmetalation, Oxidative Addition
DOI:
http://dx.doi.org/10.1039/c5cc10496c
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