| dc.contributor.author | Garcia Melchor, Max | en |
| dc.date.accessioned | 2019-08-20T14:13:07Z | |
| dc.date.available | 2019-08-20T14:13:07Z | |
| dc.date.issued | 2016 | en |
| dc.date.submitted | 2016 | en |
| dc.identifier.citation | Carrasco, D.; García-Melchor, M.; Casares, J. A.; Espinet, P., Dramatic mechanistic switch in Sn/AuI group exchanges: Transmetalation vs. oxidative addition, Chemical Communications, 52, 23, 2016, 4305 - 4308 | en |
| dc.identifier.other | Y | en |
| dc.description | PUBLISHED | en |
| dc.description.abstract | The mechanism of Ph/X exchange in reactions involving SnPh(n)Bu3 and [AuXL] complexes switches dramatically from the usual concerted mechanism involving Ar/X mixed bridges when X = Cl, to an unexpected oxidative addition/reductive elimination pathway via an Au(III) intermediate when X = vinyl. | en |
| dc.format.extent | 4305 | en |
| dc.format.extent | 4308 | en |
| dc.language.iso | en | en |
| dc.relation.ispartofseries | Chemical Communications | en |
| dc.relation.ispartofseries | 52 | en |
| dc.relation.ispartofseries | 23 | en |
| dc.rights | Y | en |
| dc.subject | Transmetalation | en |
| dc.subject | Oxidative Addition | en |
| dc.title | Dramatic mechanistic switch in Sn/AuI group exchanges: Transmetalation vs. oxidative addition | en |
| dc.type | Journal Article | en |
| dc.type.supercollection | scholarly_publications | en |
| dc.type.supercollection | refereed_publications | en |
| dc.identifier.peoplefinderurl | http://people.tcd.ie/garciamm | en |
| dc.identifier.rssinternalid | 138639 | en |
| dc.identifier.doi | http://dx.doi.org/10.1039/c5cc10496c | en |
| dc.rights.ecaccessrights | openAccess | |
| dc.identifier.rssuri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-84960881493&doi=10.1039%2fc5cc10496c&partnerID=40&md5=a374dd86679cd8d73bd8d9d8e495d786 | en |
| dc.identifier.orcid_id | 0000-0003-1348-4692 | en |
| dc.identifier.uri | http://hdl.handle.net/2262/89251 | |
